Syntheses of trehazolin, trehalamine, and the aminocyclitol moiety of trehazolin: Determination of absolute configuration of trehazolin

DOI: 10.1021/jo00083a023

Source and publish data:

Journal of Organic Chemistry p. 813 - 822 (1994)

Update date:2022-07-30

Topics:

Authors:

Kobayashi

Miyazaki

Shiozaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00083a023

The syntheses and determination of the absolute configuration of trehazolin (1), its aglycon (trehalamine (3), and its aminocyclitol hexaacetate moiety (5) are described. An important intermediate, optically active epoxide 16α, was obtained from an 11-ste

Full text of DOI:10.1021/jo00083a023

Products guided by the article

Product name:<1R-(1α,2β,3α,4β,5β)>-5-Azido-2-(benzyloxy)-1-<(benzyloxy)methyl>-3,4-bis(methoxymethoxy)-1-cyclopentanol

Cas No:144811-29-0

R&D Labs maybe for 144811-29-0

ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
Golden Union Agrochemical Import and Export Co., Ltd.

Contact:86-755-23910527

Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Nantong Kaixin Pharma Chemical Co.,Ltd.

Contact:86-513-85250786

Address:2-1103 Huachen Mansion, 111 Gongnong Road,Nantong, Jiangsu, China
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Xi'an HO-SHINE Bio-Technology Co., Ltd

Contact:+86 (29) 8248-5435/18292020086

Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China

Relevant to this article

Discovery of potent, isoform-selective inhibitors of histone deacetylase containing chiral heterocyclic capping groups and a N-(2-aminophenyl)benzamide binding unit

Doi:10.1021/jm400634n
(2013)
Stereoselective total synthesis of pinolide and its C2 epimer and evaluation of their cytotoxic activity 1

Doi:10.1055/s-0034-1379709
(2015)
NHC-Cu(I)-Catalyzed Friedl?nder-Type Annulation of Fluorinated o-Aminophenones with Alkynes on Water: Competitive Base-Catalyzed Dibenzo[b,f][1,5]diazocine Formation

Doi:10.1021/acs.joc.7b01235
(2017)
(Diisopinocampheyl)borane-mediated reductive aldol reactions of acrylate esters: Enantioselective synthesis of anti-aldols

Doi:10.1021/ol401679g
(2013)
Ferrocene phosphane-carbene ligands in Cu-catalyzed enantioselective 1,4-additions of Grignard reagents to α,β-unsaturated carbonyl compounds

Doi:10.1016/j.jorganchem.2013.03.033
(2013)
Radical-based regioselective C-H functionalization of electron-deficient heteroarenes: Scope, tunability, and predictability

Doi:10.1021/ja406223k
(2013)

Article Doi