Reaction of diphenylphosphanylacetylene with RB(C6F 5)2 reagents: Evidence for a remarkable sequence of synergistic frustrated Lewis pair addition reactions

DOI: 10.1021/ic402139g

Source and publish data:

Inorganic Chemistry p. 11661 - 11668 (2013)

Update date:2022-07-29

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Authors:

Yu, Jiangang

Kehr, Gerald

Daniliuc, Constantin G.

Erker, Gerhard

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Article abstract of DOI:10.1021/ic402139g

Diphenylphosphanylethyne (3a) reacts with tris(pentafluorophenyl)borane at room temperature by a typical frustrated Lewis pair (FLP) reaction. It undergoes a sequential series of 1,2-phosphane/borane additions to the alkyne unit in an overall 2:2 molar ra

Full text of DOI:10.1021/ic402139g

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