Syntheses of Ketene Thioselenoacetals and of γ-Unsaturated Se-Alkyl Carboxylic Thionoselenoesters

DOI: 10.1016/S0040-4039(00)60024-2

Source and publish data:

Tetrahedron Letters p. 6131 - 6134 (1992)

Update date:2022-08-03

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Authors:

Lemarie, Margareth

Vallee, Yannick

Worrell, Mark

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Article abstract of DOI:10.1016/S0040-4039(00)60024-2

The alkylation of Se-alkyl carboxylic thionoselenoesters enethiolates stereoselectively leads to ketene thioselenoacetals.When the alkylation is conducted with an allylic halide a thio-Claisen rearrangement is observed.

Full text of DOI:10.1016/S0040-4039(00)60024-2

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