Heterocycles p. 745 - 757 (2012)
Update date:2022-08-05
Topics:
Yasuda, Shigeo
Kumagai, Naoya
Shibasaki, Masakatsu
Direct asymmetric α-allylation of ketones with allylic alcohols is described. The combination of palladium with a new phosphine ligand bearing a chiral proline moiety promoted the reaction to afford the corresponding α-allylated ketones in moderate yield and enantioselectivity.
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