Palladium-catalysed Regio- and Stereo-selective Synthesis of Allylic Amines

DOI: 10.1039/c39920001498

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1498 - 1500 (1992)

Update date:2022-09-26

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Authors:

Tamaru, Yoshinao

Bando, Takashi

Kawamura, Youichi

Okamura, Kazuto

Yoshida, Zen-ichi

Shiro, Motoo

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Article abstract of DOI:10.1039/c39920001498

3-Vinyl-2,6-dioxacyclohexan-1-ones 1, by treatment with N-tosyl or N-arylisocyanates and a catalytic amount of Pd⁰, are converted into N-tosyl- and N-aryl-3-vinyl-2-aza-6-oxacyclohexan-1-ones 2 in good yields and with unique stereoselectivity.

Full text of DOI:10.1039/c39920001498

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