Journal of Organic Chemistry p. 343 - 349 (1993)
Update date:2022-07-30
Topics: Synthesis Stereoselective Application Indole Experimental Rebeccamycin N-glycosides
Gallant, Michel
Link, James T.
Danishefsky, Samuel J.
Sodium salts of indoles have been found to open α-1,2-anhydrosugars with inversion yielding indole-β-N-glycosides.This methodology constitutes a concise route from glycals to the biologically active indole-N-glycosides.An application to the total synthesis of rebeccamycin is descibed.
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(1993)Doi:10.1039/c3cc43618g
(2013)Doi:10.1139/v69-331
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(1993)
