Journal of the Chemical Society. Chemical communications p. 55 - 57 (1992)
Update date:2022-07-30
Topics:
Yamazaki, Takashi
Mizutani, Kenji
Takeda, Mitsunori
Kitazume, Tomoya
Optically active 2-butenolides with a trifluoromethyl (CF3) group are synthesized via enzymatic optical resolution and are selectively transformed into 6,6,6-trifluororhodinose and amicetose by base-promoted 1,2-migration of a tert-butyldimethylsilyl moiety in a highly efficient manner.
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