Chiral Trifluoromethylated 2-Butenolides for the Construction of 6-Deoxy-6,6,6-trifluorosugars

DOI: 10.1039/c39920000055

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 55 - 57 (1992)

Update date:2022-07-30

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Authors:

Yamazaki, Takashi

Mizutani, Kenji

Takeda, Mitsunori

Kitazume, Tomoya

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Article abstract of DOI:10.1039/c39920000055

Optically active 2-butenolides with a trifluoromethyl (CF3) group are synthesized via enzymatic optical resolution and are selectively transformed into 6,6,6-trifluororhodinose and amicetose by base-promoted 1,2-migration of a tert-butyldimethylsilyl moiety in a highly efficient manner.

Full text of DOI:10.1039/c39920000055

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