Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 891 - 894 (1992)
Update date:2022-08-05
Topics:
Yurtanov, A. I.
Adkhamova, Z. M.
Baidildaeva, S. K.
The corresponding carbamic acid derivatives were obtained (28-91percent) yields) as a result of the reaction of dichloronitroacetic acid derivatives, O2NCCl2COR, (1a-c, R=OEt, OCH2Ph, NH2) with ammonia, methylamine, benzylamine, glycine, phenylhydrazine, and aniline. The probable mechanism of the process and factors that affect the nature of the departing group were discussed. Keywords: dichloronitroacetic acid derivatives, aminolysis, intermediate states, mechanisms of reactions.
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