Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 253 - 259 (1992)
Update date:2022-09-26
Topics:
Arbuzov, B. A.
Karasik, A. A.
Nikonov, G. N.
Malova, E. V.
Khadiullin, R. Sh.
et al.
1,3,5-Diazaphosphorinanes and 1,5,3,7-diazadiphosphacyclooctanes form complexes with Pt(II), Pd(II), Cu(I), and Ag(I) salts.Platinum and palladium are coordinated through phosphorous atoms.In the case of 1,3-diphenyl-5-p-toluidenomethyl-1,3,5-diazaphosphorinane complex formation with platinum and palladium is accompanied by formation of a new polydentate ligand, p-tolylbis-(1,3-di-p-tolyl-1,3,5-diazaphosphorinane-5-yl)methylamine, where the metal is also bonded to phosphorus atoms. Keywords: 1,3,5-diazaphosphorinanes, 1,5,3,7-diazadiphosphacyclooctanes, complexes, platinum, palladium, ring conformation.
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