COMPLEXES OF CYCLIC AMINOMETHYLPHOSPHINES WITH Pt(II), Pd(II), Cu(I), AND Ag(I) SALTS

Article abstract of DOI:10.1007/BF00869510

1,3,5-Diazaphosphorinanes and 1,5,3,7-diazadiphosphacyclooctanes form complexes with Pt(II), Pd(II), Cu(I), and Ag(I) salts.Platinum and palladium are coordinated through phosphorous atoms.In the case of 1,3-diphenyl-5-p-toluidenomethyl-1,3,5-diazaphosphorinane complex formation with platinum and palladium is accompanied by formation of a new polydentate ligand, p-tolylbis-(1,3-di-p-tolyl-1,3,5-diazaphosphorinane-5-yl)methylamine, where the metal is also bonded to phosphorus atoms. Keywords: 1,3,5-diazaphosphorinanes, 1,5,3,7-diazadiphosphacyclooctanes, complexes, platinum, palladium, ring conformation.