Diastereoselectivity in the Osmium Tetraoxide Promoted Dihydroxylation of Chiral (E)-Crotylsilanes: Asymmetric Synthesis of Silyl-Functionalized γ-Lactones

DOI: 10.1021/jo00054a002

Source and publish data:

Journal of Organic Chemistry p. 294 - 296 (1993)

Update date:2022-09-26

Topics:

Authors:

Panek, James S.

Zhang, Jing

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00054a002

The catalytic osmylation of enantiomerically enriched (E)-crotylsilanes (2S,3R)-1 and (2R,3R)-2 containing a homoallylic, nitrogen-bearing stereocenter proceeds with good to high levels of diastereoselection generating silyl-functionalized trans-4,5-subst

Full text of DOI:10.1021/jo00054a002

Products guided by the article

Product name:N-[(3S,4S,5R)-4-(Dimethyl-phenyl-silanyl)-5-((S)-1-hydroxy-ethyl)-2-oxo-tetrahydro-furan-3-yl]-acetamide

Cas No:146328-57-6

R&D Labs maybe for 146328-57-6

Mashilabs(shanghai)Co.,ltd

Contact:+86-21-54391580

Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area

Relevant to this article

The Application of Levulinic Acid and 5-Nitro-2-furylmethylene Diacetate in the Total Synthesis of Some Novel Biologically Active (5-Nitro-2-furyl)azomethines

Doi:10.1007/BF00808957
(1990)
Carbon isotope labeling of carbamates by late-stage [¹¹C], [¹³C] and [¹⁴C]carbon dioxide incorporation

Doi:10.1039/d0cc05031h
(2020)
Enantioselective synthesis of β-amino acids. 4. 1,2 asymmetric induction in the alkylation of 1-benzoyl-3,6(S)-dimethylperhydropyrimidin-4-one. Preparation of the like and unlike stereoisomers of 2-methyl- and 2-benzyl-3(S)-aminobutanoic acid

Doi:10.1021/jo00060a051
(1993)
Fluorous phthalocyanines and subphthalocyanines

Doi:10.1142/S1088424620500182
(2020)
SYNTHESIS AND STRUCTURE OF 3-AMINO-4-HETARYL-1(2H)-ISOQUINOLONES

Doi:10.1007/BF00472292
(1991)
Activation of Benzyl Aryl Carbonates: The Role of Cation-π Interactions

Doi:10.1021/acs.joc.6b00441
(2016)

Article Doi