Diastereoselectivity in the Osmium Tetraoxide Promoted Dihydroxylation of Chiral (E)-Crotylsilanes: Asymmetric Synthesis of Silyl-Functionalized γ-Lactones

DOI: 10.1021/jo00054a002

Source and publish data:

Journal of Organic Chemistry p. 294 - 296 (1993)

Update date:2022-09-26

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Authors:

Panek, James S.

Zhang, Jing

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Article abstract of DOI:10.1021/jo00054a002

The catalytic osmylation of enantiomerically enriched (E)-crotylsilanes (2S,3R)-1 and (2R,3R)-2 containing a homoallylic, nitrogen-bearing stereocenter proceeds with good to high levels of diastereoselection generating silyl-functionalized trans-4,5-subst

Full text of DOI:10.1021/jo00054a002

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Article Doi

Diastereoselectivity in the Osmium Tetraoxide Promoted Dihydroxylation of Chiral (E)-Crotylsilanes: Asymmetric Synthesis of Silyl-Functionalized γ-Lactones

DOI: 10.1021/jo00054a002

Source and publish data:

Authors:

Article abstract of DOI:10.1021/jo00054a002

Full text of DOI:10.1021/jo00054a002

Products guided by the article

R&D Labs maybe for 146328-57-6

Relevant to this article

The Application of Levulinic Acid and 5-Nitro-2-furylmethylene Diacetate in the Total Synthesis of Some Novel Biologically Active (5-Nitro-2-furyl)azomethines

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Enantioselective synthesis of β-amino acids. 4. 1,2 asymmetric induction in the alkylation of 1-benzoyl-3,6(S)-dimethylperhydropyrimidin-4-one. Preparation of the like and unlike stereoisomers of 2-methyl- and 2-benzyl-3(S)-aminobutanoic acid

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