Diastereoselectivity in the Osmium Tetraoxide Promoted Dihydroxylation of Chiral (E)-Crotylsilanes: Asymmetric Synthesis of Silyl-Functionalized γ-Lactones

DOI: 10.1021/jo00054a002

Source and publish data:

Journal of Organic Chemistry p. 294 - 296 (1993)

Update date:2022-09-26

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Authors:

Panek, James S.

Zhang, Jing

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Article abstract of DOI:10.1021/jo00054a002

The catalytic osmylation of enantiomerically enriched (E)-crotylsilanes (2S,3R)-1 and (2R,3R)-2 containing a homoallylic, nitrogen-bearing stereocenter proceeds with good to high levels of diastereoselection generating silyl-functionalized trans-4,5-subst

Full text of DOI:10.1021/jo00054a002

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