Copper Monooxygenase Models: Hydroxylation Reactions resulting from Dioxygen Activation by Copper(I) Complexes

DOI: 10.1039/c39920001782

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Journal of the Chemical Society. Chemical communications p. 1782 - 1784 (1992)

Update date:2022-08-04

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Authors:

Amadei, Edith

Alilou, El Houssine

Eydoux, Franck

Pierrot, Marcel

Reglier, Marius

Waegell, Bernard

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Article abstract of DOI:10.1039/c39920001782

We describe the synthesis and reactivity of new mononuclear copper(I) complexes 4a-c, which can be considered to be copper monooxygenase models and can be used to achieve hydroxylation of aliphatic C-H bonds by dioxygen activation.

Full text of DOI:10.1039/c39920001782

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Product name:{Cu(C₅H₄N(C₂H₄N(C₂H₄C₅H₄N)C₂H₄CON(CH₃)C₂H₄C₆H₅))}⁽¹⁺⁾*PF₆^(1-)={Cu(C₅H₄N(C₂H₄N(C₂H₄C₅H₄N)C₂H₄CON(CH₃)C₂H₄C₆H₅))}PF₆

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