Synthesis p. 1137 - 1144 (1992)
Update date:2022-09-26
Topics:
Effenberger
Niesert
The synthesis of terminally donor-acceptor substituted polyenes from the respective aldehydes via Horner reactions is described. As donor group the 9-anthryl and as acceptor moiety the 4-(N-methyl)pyridinium residue were chosen. A bicyclo[2.2.2]octane unit was incorporated into the chain to interrupt the conjugation. The separation and characterization of the mixtures of Z/E-isomers obtained in the syntheses was possible.
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Doi:10.1055/s-0034-1379933
(2015)Doi:10.1016/S0040-4039(00)60567-1
(1993)Doi:10.1021/jo026514t
(2003)Doi:10.1021/jo00064a043
(1993)Doi:10.1021/acs.joc.9b03434
(2020)Doi:10.1021/ja00977a020
(1967)
