Journal of the Chemical Society. Perkin transactions II p. 1853 - 1856 (1995)
Update date:2022-09-26
Topics:
Belohradsky, Martin
Holy, Petr
Zavada, Jiri
A very pronounced effect of solvent and cation has been found in the investigated reaction, indicating that ion-pairing is indispensable in the product formation.A simple rationale has been provided assuming self-assembly of the complementary reactants driven by hydrogen bonding and ion-pairing interactions.Concomitantly, halogen exchange between the reaction partners has been demonstrated to be a concurrent pathway, resulting from the nucleophilic 2-napthoxide attack at the bromide terminus of the Cα-Br bond in the participating 1-bromo-2-naphthol.
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