Journal of the Chemical Society, Dalton Transactions p. 35 - 42 (1993)
Update date:2022-08-04
Topics:
Sheehan, James P.
Spalding, Trevor R.
Ferguson, George
Gallagher, John F.
Kaitner, Branko
Kennedy, John D.
The reaction of Aga = 14.073, b = 15.640(2), c = 20.262(6) Angstroem and β = 94.80(2) deg.A final R factor of 0.038 was claculated for 5595 observed reflections.The Pd-OH2 distance is 2.208(4) Angstroem and Pd-P(1) is 2.3544(14) Angstroem.Cage interatomic distances include Pd-Te 2.6958(6) and ranges for Pd-B of 2.192(6)-2.299(6) and Te-B of 2.287(6)-2.403(6) Angstroem.The exo-cage B(7)-P(2) distance is 1.950(6) Angstroem.The water molecule in 2 can be displaced by a variety of ligands to produce the cationic palladatelluraborane complexes <2-L-2-(PPh3)-closo-2,1-PdTeB10H9(PPh3)>a tenfold excess of PMe2Ph affords <2,2-(PMe2Ph)2-closo-2,1-PdTeB10H9(PPh3)>a = 14.509(3), b = 10.732(1), c = 31.377(8) Angstroem and β = 97.49(2) deg.The final R factor of 0.054 was calculated from 5439 observed reflections.Principal interatomic distances include Pd-Te 2.6897(9), Pd-B 2.195(10)-2.307(9), Te-B 2.262(11)-2.389(9).Pd-P(2) 2.367(2), B(11)-P(1) 1.941(9) and Pd-C(1) 2.003(9) Angstroem.
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