REACTIONS OF AZIRIDINE-2-CARBOXYLIC ACID DERIVATIVES WITH ESTERS AND NITRILES OF UNSATURATED ACIDS

Article abstract of DOI:10.1007/BF00516205

Products of addition to the multiple bond were obtained in the reaction of the methyl ester, nitrile, and amide of aziridine-2-carboxylic acid with esters or nitriles of acrylic acid and esters of maleic, acetylenemonocarboxylic, and acetylenedicarboxylic acids.The bromination of 1-(2-alkoxycarbonylethenyl)-2-methoxycarbonylaziridines under various conditions leads to the addition of bromine to the multiple bond with retention or opening of the aziridine ring.