Ortho-Selective Side-Chain Nitration of α-Bromoacylpolymethylbenzenes and its Application to the Syntheses of Indan-1-one and Inden-1-one Derivatives

DOI: 10.1016/S0040-4020(01)86258-X

Source and publish data:

Tetrahedron p. 537 - 556 (1993)

Update date:2022-08-05

Topics:

Authors:

Keumi, Takashi

Matsuura, Kazunori

Nakayama, Norihiro

Tsubota, Toshiaki

Morita, Toshio

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)86258-X

α-Bromoacylpolymethylbenzenes 2a - m react with fuming nitric acid in acetic anhydride to give 2-(nitromethyl)-(α-bromoacyl)polymethylbenzenes 3a - m in good isolated yields.Compounds 3a - j undergo the intramolecular nucleophilic substitution/cyclization

Full text of DOI:10.1016/S0040-4020(01)86258-X

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