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The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent To a Stereogenic Centre: Diastereoselective Alkylation and Protonation of Open-chain Enolates Having a Stereogenic Centre Carrying a Silyl Group at the β Position

DOI: 10.1039/P19920003277

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3277 - 3294 (1992)

Update date:2022-08-03

Topics:

Authors:

Crump, Roger A. N. C.Crump, Roger A. N. C.

Fleming, IanFleming, Ian

Hill, John H. M.Hill, John H. M.

Parker, DavidParker, David

Reddy, N. LaxmaReddy, N. Laxma

Waterson, DavidWaterson, David

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Article abstract of DOI:10.1039/P19920003277

The alkylation and protonation of enolates having a β-silyl group, prepared by conjugate addition of a silyl-cuprate reagent to enone systems, are almost always highly diastereoselective in the sense 3 in a wide variety of reactions.The effects of varying

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Product name:methyl (RS)-3-phenyl-3-triphenylsilylpropanoate

Cas No:148004-14-2

148004-14-2

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