A search for maximal neighboring group participation in Solvolyses of allylic substrates. Ethanolysis of 2-(ω-alkylthioalkyl)-3-methyl-2-cyclohexenyl p-nitrobenzoates

DOI: 10.1016/S0040-4020(01)86349-3

Source and publish data:

Tetrahedron p. 2717 - 2728 (1993)

Update date:2022-07-31

Topics:

Authors:

Jursic, Branko S.

Ladika, Mladen

Sunko, Dionis E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86349-3

The solvolysis of 2-(ω-methylthioalkyl)- and 2-(ω-benzylthioalkyl)-3-methyl-2-cyclohexenyl p-nitrobenzoates 5 and 6 in 80 vol % ethanol includes several competitive reactions. Path k₁ is a stepwise process (k_H/k_D = 1.18-1.

Full text of DOI:10.1016/S0040-4020(01)86349-3

Products guided by the article

Product name:4-Methyl-2,3,5,6,7,7a-hexahydro-benzo[b]thiophene

Cas No:148043-66-7

R&D Labs maybe for 148043-66-7

Tradlon Chemical Co., Ltd.

Contact:+86-710-3516804

Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
nanjing suru chemical co.ltd

Contact:+86-025-52406782

Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China

Relevant to this article

NOVEL REACTIVITY OF 2-(CHLOROMETHOXY)ETHYL ACETATE

Doi:10.1016/S0040-4039(00)84811-X
(1986)
Investigation of Electronic Effects in the Pyridine and Pyridine N-Oxide Rings. Part 4. Kinetics and Mechanism of the Reaction of Diazodiphenylmethane with Substituted Carboxypyridine and 2-carboxypyridine N-Oxides in Dimethylforamide

Doi:10.1039/P29840001975
(1984)
Mono- and dinuclear cobalt complexes with chelating or bridging bidentate P,N phosphino- and phosphinito-oxazoline ligands: Synthesis, structures and catalytic ethylene oligomerisation

Doi:10.1039/b706818b
(2007)
Nickel-Catalyzed Domino Heck-Type Reactions Using Methyl Esters as Cross-Coupling Electrophiles

Doi:10.1002/anie.201911372
(2019)
Solvent-free addition of ethynylbenzene to ketones

Doi:10.1246/bcsj.74.185
(2001)
Formation of chelated counteranions using lewis acidic diboranes: Relevance to isobutene polymerization

Doi:10.1021/om700672q
(2007)

Article Doi