Tetrahedron Letters p. 3417 - 3420 (1986)
Update date:2022-07-31
Topics:
Aitken, David J.
Rees, Lilias
Suckling, Colin J.
Wood, Hamish C. S.
2-(Chloromethoxy)ethyl acetate reacts with alcohols in the presence of silver carbonate to produce 2-(alkoxymethoxy)ethyl acetates and bis(alkoxy)methanes.A mechanism which involves neighboring group participation of a chloromethyl ether oxygen atom is proposed to account for the formation of the latter products.
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