
Bulletin of the Chemical Society of Japan p. 3239 - 3246 (1996)
Update date:2022-08-04
Topics:
Itahara, Toshio
Treatment of pyrimidine bases such as uracil, thymine, and 5-fluorouracil with X(CH2)nX (X=I or Br; n=4-12) gave three types of pyrimidinophanes. When the numbers of carbon atoms of X(CH2)nX are odd numbers (n=5, 7, 9, 11), three structures of pyrimidinophanes could be differentiated on the basis of the 13C NMR and mass spectra. Treatment of pyrimidinophanes with 1,4-naphthoquinone or maleimides in the presence of palladium(II) acetate gave the coupling products. Reaction of pyrimidinophanes with NaNO2 in the presence of palladium(II) acetate led to the nitration.
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Doi:10.1021/ja00063a001
(1993)Doi:10.1039/c39930000337
(1993)Doi:10.1016/S0957-4166(00)86019-X
(1993)Doi:10.1007/BF00908498
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(1993)Doi:10.1021/jo00061a034
(1993)