Generation, Some Synthetic Uses, and 1,2-Vinyl Rearrangements of Secondary and Tertiary Homoallyllithiums, Including Ring Contractions and A Ring Expansion. Remarkable Acceleration of the Rearrangement by an Oxyanionic Group

DOI: 10.1021/ja00063a001

Source and publish data:

Journal of the American Chemical Society p. 3855 - 3865 (1993)

Update date:2022-08-04

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Authors:

Mudryk, Boguslaw

Cohen, Theodore

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Article abstract of DOI:10.1021/ja00063a001

A very general preparative method for homoallyllithiums consists of reductive lithiation of homoallylithiums consists of reductive lithiation of homoallyl phenyl sulfides by lithium 4,4'-di-tert-butylbiphenylide.The sulfides can be prepared by a variety o

Full text of DOI:10.1021/ja00063a001

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