tert-Butyldimethylsilyldichloromethyllithium as a dichloromethylene dianion synthon. 1,3-Rearrangement of silyl group from carbon to oxide

DOI: 10.1016/S0040-4039(00)91972-5

Source and publish data:

Tetrahedron Letters p. 1951 - 1954 (1993)

Update date:2022-08-03

Topics:

Authors:

Shinokubo, Hiroshi

Miura, Katsukiyo

Oshima, Koichiro

Utimoto, Kiitiro

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One-pot synthesis of R¹CH(OSiMe₂-t-Bu)CCl₂CH(OH)R² by successive addition of two different electrophiles has been achieved starting.

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