tert-Butyldimethylsilyldichloromethyllithium as a dichloromethylene dianion synthon. 1,3-Rearrangement of silyl group from carbon to oxide

DOI: 10.1016/S0040-4039(00)91972-5

Source and publish data:

Tetrahedron Letters p. 1951 - 1954 (1993)

Update date:2022-08-03

Topics:

Authors:

Shinokubo, Hiroshi

Miura, Katsukiyo

Oshima, Koichiro

Utimoto, Kiitiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

One-pot synthesis of R¹CH(OSiMe₂-t-Bu)CCl₂CH(OH)R² by successive addition of two different electrophiles has been achieved starting.

Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
Water Chemical Co.,LTD

Contact:+86-21-6856-1349 523-87676172

Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province
Skyrun Industrial Co.,Ltd(expird)

website:http://www.chinaskyrun.com

Contact:0086-576-84610586

Address:Chemical Development Zone
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China