Allylsilanes derived from aminoacids in the synthesis of piperidine and pyrrolidins derivatives

DOI: 10.1016/S0040-4039(00)91794-5

Source and publish data:

Tetrahedron Letters p. 1355 - 1358 (1993)

Update date:2022-07-31

Topics:

Authors:

Franciotti, Maurizio

Mann, Andre

Mordini, Alessandro

Taddei, Maurizio

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Article abstract of DOI:10.1016/S0040-4039(00)91794-5

Allylsilanes preapared from α-aminoacids react with acyl chlorides in the presence of TiCl₄ to give unsaturated amino ketones, easily transformed into pyrrolidine derivatives, whereas addition to aldehydes gave 2,6-disubstituted tetrahydropyrid

Full text of DOI:10.1016/S0040-4039(00)91794-5

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