Studies on chiral organosulfur compounds. VI. The use of a chiral diene bearing an optically active sulfinylmethyl group in the Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction

DOI: 10.1248/cpb.45.759

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 759 - 764 (1997)

Update date:2022-09-26

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Authors:

Hiroi, Kunio

Umemura, Masayuki

Tomikawa, Yoko

Kaneko, Masamitsu

Kato, Fumiko

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Article abstract of DOI:10.1248/cpb.45.759

An asymmetric Diels-Alder reaction with a diene bearing a chiral sulfinyl group is described. The Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction of a chiral α'-sulfinyl-α,β- unsaturated ketone derived from 3-methylcitronellal p

Full text of DOI:10.1248/cpb.45.759

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