Studies on chiral organosulfur compounds. VI. The use of a chiral diene bearing an optically active sulfinylmethyl group in the Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction

DOI: 10.1248/cpb.45.759

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 759 - 764 (1997)

Update date:2022-09-26

Topics:

Authors:

Hiroi, Kunio

Umemura, Masayuki

Tomikawa, Yoko

Kaneko, Masamitsu

Kato, Fumiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.45.759

An asymmetric Diels-Alder reaction with a diene bearing a chiral sulfinyl group is described. The Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction of a chiral α'-sulfinyl-α,β- unsaturated ketone derived from 3-methylcitronellal p

Full text of DOI:10.1248/cpb.45.759

NII-Electronic Library Service

Products guided by the article

Product name:(4aS,8aR,R_S)-4a,5,6,7,8,8a-hexahydro-1,1,6,6-tetramethyl-2-(p-toluenesulfinylmethyl)-1H-2-benzopyran

Cas No:148587-67-1

R&D Labs maybe for 148587-67-1

Haitong Chemical Industrial Co.,Ltd.

website:https://www.haitonglongwin.com/

Contact:+86-022-66221018

Address:18-701, No.99, The 4th Street, TEDA,
Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.

Relevant to this article

Synthetic studies on pentacyclic aromatic alkaloids, kuanoniamine A, 11-hydroxyascididemin, and neocalliactine acetate

Doi:10.1016/S0040-4020(97)10153-3
(1997)
Synthesis, transition temperatures and some physical properties of some low-melting smectic materials

Doi:10.1080/10587259508038688
(1995)
Stabilized analogs of thymopentin. 2. 1,2- and 3,4-ketomethylene pseudopeptides

Doi:10.1021/jm9508043
(1997)
Synthesis of Methylene-Bridged Polycyclic Aromatic Hydrocarbons: An Efficient, Double Friedel-Crafts Cyclization Approach to 11H-Benzaceanthrylene

Doi:10.1021/jo00073a058
(1993)
The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine

Doi:10.1021/ja9606440
(1996)
Synthesis, structural characterization, and reactivity of mono(amidinate) rare-earth-metal bis(aminobenzyl) complexes

Doi:10.1021/om400787j
(2013)

Article Doi