Studies on chiral organosulfur compounds. VI. The use of a chiral diene bearing an optically active sulfinylmethyl group in the Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction

DOI: 10.1248/cpb.45.759

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 759 - 764 (1997)

Update date:2022-09-26

Topics:

Authors:

Hiroi, Kunio

Umemura, Masayuki

Tomikawa, Yoko

Kaneko, Masamitsu

Kato, Fumiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.45.759

An asymmetric Diels-Alder reaction with a diene bearing a chiral sulfinyl group is described. The Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction of a chiral α'-sulfinyl-α,β- unsaturated ketone derived from 3-methylcitronellal p

Full text of DOI:10.1248/cpb.45.759

NII-Electronic Library Service

Products guided by the article

Product name:(4aS,8aR,R_S)-4a,5,6,7,8,8a-hexahydro-1,1,6,6-tetramethyl-2-(p-toluenesulfinylmethyl)-1H-2-benzopyran

Cas No:148587-67-1

R&D Labs maybe for 148587-67-1

Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD

Contact:+86-22-25210964

Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
CHEMINN LTD.

website:http://www.cheminn.com/

Contact:86-531-67875205

Address:No.9-2,South of Shanda Road, Jinan ,China
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Suzhou Credit International Trading Co., Ltd

Contact:+86-512-65398039

Address:Qingdeng, Hightech. District, Suzhou

Relevant to this article

Synthetic studies on pentacyclic aromatic alkaloids, kuanoniamine A, 11-hydroxyascididemin, and neocalliactine acetate

Doi:10.1016/S0040-4020(97)10153-3
(1997)
Synthesis, transition temperatures and some physical properties of some low-melting smectic materials

Doi:10.1080/10587259508038688
(1995)
Stabilized analogs of thymopentin. 2. 1,2- and 3,4-ketomethylene pseudopeptides

Doi:10.1021/jm9508043
(1997)
Synthesis of Methylene-Bridged Polycyclic Aromatic Hydrocarbons: An Efficient, Double Friedel-Crafts Cyclization Approach to 11H-Benzaceanthrylene

Doi:10.1021/jo00073a058
(1993)
The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine

Doi:10.1021/ja9606440
(1996)
Synthesis, structural characterization, and reactivity of mono(amidinate) rare-earth-metal bis(aminobenzyl) complexes

Doi:10.1021/om400787j
(2013)

Article Doi