Studies on chiral organosulfur compounds. VI. The use of a chiral diene bearing an optically active sulfinylmethyl group in the Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction

DOI: 10.1248/cpb.45.759

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 759 - 764 (1997)

Update date:2022-09-26

Topics:

Authors:

Hiroi, Kunio

Umemura, Masayuki

Tomikawa, Yoko

Kaneko, Masamitsu

Kato, Fumiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.45.759

An asymmetric Diels-Alder reaction with a diene bearing a chiral sulfinyl group is described. The Lewis acid-catalyzed intramolecular asymmetric hetero Diels-Alder reaction of a chiral α'-sulfinyl-α,β- unsaturated ketone derived from 3-methylcitronellal p

Full text of DOI:10.1248/cpb.45.759

NII-Electronic Library Service

Products guided by the article

Product name:(4aS,8aR,R_S)-4a,5,6,7,8,8a-hexahydro-1,1,6,6-tetramethyl-2-(p-toluenesulfinylmethyl)-1H-2-benzopyran

Cas No:148587-67-1

R&D Labs maybe for 148587-67-1

hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549
Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Beijing Harmony Chemical Co., Ltd.

Contact:86-010-84956928

Address:Room 207, Jin feng he B building, No 8 Xin Jie Kou Wai Street, Xi Cheng District, Beijing,PRC. 10008
SHANGHAI T&W PHARMACEUTICAL CO., LTD.

website:http://www.trustwe.com

Contact:+86-21-61551413

Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China

Relevant to this article

Synthetic studies on pentacyclic aromatic alkaloids, kuanoniamine A, 11-hydroxyascididemin, and neocalliactine acetate

Doi:10.1016/S0040-4020(97)10153-3
(1997)
Synthesis, transition temperatures and some physical properties of some low-melting smectic materials

Doi:10.1080/10587259508038688
(1995)
Stabilized analogs of thymopentin. 2. 1,2- and 3,4-ketomethylene pseudopeptides

Doi:10.1021/jm9508043
(1997)
Synthesis of Methylene-Bridged Polycyclic Aromatic Hydrocarbons: An Efficient, Double Friedel-Crafts Cyclization Approach to 11H-Benzaceanthrylene

Doi:10.1021/jo00073a058
(1993)
The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine

Doi:10.1021/ja9606440
(1996)
Synthesis, structural characterization, and reactivity of mono(amidinate) rare-earth-metal bis(aminobenzyl) complexes

Doi:10.1021/om400787j
(2013)

Article Doi