Synthesis of Glycosylphosphine Oxides and Related Compounds

DOI: 10.1002/hlca.19930760104

Source and publish data:

Helvetica Chimica Acta p. 94 - 112 (1993)

Update date:2022-08-02

Topics:

Authors:

Lopusinski, Andrej

Bernet, Bruno

Linden, Anthony

Vasella, Andrea

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Article abstract of DOI:10.1002/hlca.19930760104

The benzyl-protected glycosyl acetates 1, 6, 11, and 15 react with MeOPPh2 under catalysis by TMSOTf to yield diastereoselectively the glycosylphosphine oxides 2, 3, 8, 12, 13, and 16, with a strong preference for the 1,2-cis-configurated anomers.Hydrogen

Full text of DOI:10.1002/hlca.19930760104

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