A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of α,β-unsaturated ketones to allylic alcohol

DOI: 10.1016/j.tetlet.2013.10.051

Source and publish data:

Tetrahedron Letters p. 7013 - 7016 (2013)

Update date:2022-09-26

Topics:

Authors:

Lu, Sheng-Mei

Gao, Qiang

Li, Jun Li, Jun

Liu, Yan

Li, Can Li, Can

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Article abstract of DOI:10.1016/j.tetlet.2013.10.051

A robust and stable Ru-Biphosphinobioxazoline catalyst system is discovered for the highly enantioselective hydrogenation of enones to allylic alcohols. A series of acyclic α,β-unsaturated ketones react well affording the desired products in high yields (

Full text of DOI:10.1016/j.tetlet.2013.10.051

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