Stereoselective synthesis of 1,2-cis- and 2-deoxyglycofuranosyl azides from glycosyl halides

Article abstract of DOI:10.1016/S0008-6215(00)00186-5

Protected 1,2-cis glycofuranosyl azides with α-D-ribo, β-D-arabino and 2-deoxy-2-fluoro-β-D-arabino configurations were efficiently prepared from the appropriate 1,2-trans glycosyl halides bearing non-participating O-2 substituent by inversion with sodium