
Journal of the American Chemical Society p. 5466 - 5478 (1993)
Update date:2022-08-05
Topics: Intramolecular Cycloaddition Activation Parameters Hydrogen Transfer
Peterson, Thomson H.
Carpenter, Barry K.
The biradical 2-methyl-2-(3-phenylpropyl)cyclopentane-1,3-diyl is reversibly by gas-phase pyrolysis of a stereoisomeric mixture of the corresponding bicyclo[2.1.0]pentane derivatives. Three reactions of the biradical (besides ring closure) are detected. O
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