Substituent effects in the reaction of allyl trichloroacetimidates with N-halosuccinimides: Cyclization vs aza-Claisen rearrangement.

DOI: 10.1016/S0040-4039(97)10837-1

Source and publish data:

Tetrahedron Letters p. 1465 - 1468 (1998)

Update date:2022-08-03

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Authors:

Shabany, Hossein

Spilling, Christopher D.

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Article abstract of DOI:10.1016/S0040-4039(97)10837-1

We report a novel substituent effect in the reaction of allylic trichloroacetimidates with N-halosuccinimides. Reaction of E allylic trichloroacetimidates bearing phosphonate or cyano substituents with NBS in CHCI₃ results in a [3.3] sigmatropi

Full text of DOI:10.1016/S0040-4039(97)10837-1

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