Tertiary Phosphine Adducts of

DOI: 10.1039/DT9930001657

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1657 - 1660 (1993)

Update date:2022-09-26

Topics:

Authors:

Gibson, Vernon C.

Kee, Terence P.

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Article abstract of DOI:10.1039/DT9930001657

A series of tertiary phosphine adducts of is described.The compounds (L = PMe3, PMePh2, PPh3 or PEt3), and have been prepared via reaction of either <n> or (thf = tetrahydrofuran) with a stoichiometric amount of the phosphine in dichloromethane solvent.The influence of the differing ligand fields on the infrared stretching frequency of the niobium-oxygen bond is discussed in terms of the geometry of the complex and the stereoelectronic properties of the attendant ligands.

Full text of DOI:10.1039/DT9930001657

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