Synthesis of L-ornithines stereospecifically deuterated at C-3

DOI: 10.1016/S0040-4039(00)79263-X

Source and publish data:

Tetrahedron Letters p. 3919 - 3920 (1993)

Update date:2022-08-05

Topics: -Synthesis -Deuterated

Authors:

Baldwin Baldwin

Merritt Merritt

Schofield

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Article abstract of DOI:10.1016/S0040-4039(00)79263-X

(2S, 3S)-[2,3-²H₂]-Ornithine and (2S, 3R)-[3-²H₁]-ornithine were prepared with high stereoselectivity via asymmetric reduction catalysed by {bicyclo[2.2.1]hepta-2,5-diene}{(R)-1,2-bis(diphenylphosphino)propa ne}rhodium (I) trifluoromethanesulphonate [(R)-Rh-Prophos].

Full text of DOI:10.1016/S0040-4039(00)79263-X

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