Stereoselective Synthesis of Trans Isomers of a Volatile Compound Isolated from the Elm Bark Beetle "Pteleobius vittatus" via Stereospecific Cyclodehydration Route

DOI: 10.1246/bcsj.66.1738

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1738 - 1742 (1993)

Update date:2022-08-05

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Authors:

Chikashita, Hidenori

Hirao, Kiyoharu

Itoh, Kazuyoshi

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Article abstract of DOI:10.1246/bcsj.66.1738

The stereoselective asymmetric synthesis of two trans isomers of the title natural product, (3R,6R)- and (3S,6S)-tetrahydro-2,2,6-trimethyl-2H-pyran-3-ol, was achieved by starting with easily obtainable ethyl (S)-3-hydroxybutanoate, via the stereospecific

Full text of DOI:10.1246/bcsj.66.1738

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