Dimethyldioxirane epoxidation of benzofurans: Reversible thermal and photochemical valence isomerization between benzofuran epoxides, quinone methides, and benzoxetenes

DOI: 10.1021/ja00072a012

Source and publish data:

Journal of the American Chemical Society p. 8603 - 8608 (1993)

Update date:2022-08-04

Topics:

Authors:

Adam, Waldemar

Hadjiarapoglou, Lazaros

Peters, Karl

Sauter, Markus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00072a012

Low-temperature oxidation of the four possible regioisomeric methoxy-substituted benzofurans 1 by dimethyldioxirane afforded the rather labile epoxides 2, which are in equilibrium with their equally labile quinone methides 3 through reversible valence iso

Full text of DOI:10.1021/ja00072a012

Products guided by the article

Product name:6-(1'-methyl-1'-acetylmethylene)-3-methoxy-2,4-cyclohexadienone

Cas No:150969-68-9

R&D Labs maybe for 150969-68-9

Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com

Relevant to this article

Methoxy-poly(ethylene glycol)-block-poly(ε-caprolactone) bearing pendant aldehyde groups as pH-responsive drug delivery carrier

Doi:10.1071/CH13297
(2013)
Oligonucleotides Containing a Covalent Conformationally Restricted Phosphodiester Analog for High-Affinity Triple Helix Formation: The Riboacetal Internucleotide Linkage

Doi:10.1021/ja00074a065
(1993)
Mechanism of Arylation of Nucleophiles by Aryllead Triacetates. Part 2. Support for a Ligand Coupling Process and X-Ray Molecular Structure of (p-Methoxyphenyl)-α-methylphenacyllead(IV) Diacetate

Doi:10.1039/P19930001677
(1993)
Mechanistic analysis of the 3-methyllumiflavin-promoted oxidative deamination of benzylamine. A potential model for monoamine oxidase catalysis

Doi:10.1021/ja00076a017
(1993)
π-Delocalization in the vicinal lone pairs of hydrazines: Electronic effects in derivatives of 1-(2-nitrophenyl)-1-phenylhydrazine

Doi:10.1016/j.molstruc.2016.02.061
(2016)
Resonance Raman studies of dioxygen binding to ortho-substituted tetraphenyl- and tetranaphthyl-porphyrinatoiron(II) derivatives with a covalently linked axial imidazole

Doi:10.1039/a802925c
(1998)

Article Doi