The Use of the Novel Oxidising Reagent Triphenylarsine Diiodine in the Reaction with Dicobalt Octacarbonyl to produce a New Type of Complex

DOI: 10.1039/c39930001190

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1190 - 1191 (1993)

Update date:2022-08-04

Topics:

Authors:

Godfrey, Stephen M.

Lane, Helen P.

Mackie, Anthony G.

McAuliffe, Charles A.

Pritchard, Robin G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001190

Ph3AsI2 oxidises Co2(CO)8 in a 6:1 molar ratio to produce the novel complex <(Ph3AsI)2I> in quantitative yield, the first crystallographically characterised complex containing a cobalt(II)-tertiary arsine bond and the unusual linear cation ⁺.

Full text of DOI:10.1039/c39930001190

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{((C₆H₅)3As)2I₃}⁽¹⁺⁾*{Co(As(C₆H₅)3)I₃}^(1-)={((C₆H₅)3As)2I₃}{Co(As(C₆H₅)3)I₃}

Cas No:150997-63-0

R&D Labs maybe for 150997-63-0

Deltachem(QingDao)Co.,Ltd.

Contact:+8618766299236

Address:ROOM808, BUILDING2,NO.230 SHEN ZHEN ROAD, LAOSHAN DISTRICT
Quhua Zhongxing Refrigeration Technology Co.,Ltd.

Contact:+86-5708886618

Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China

Relevant to this article

Dynamic kinetic resolution of allylic sulfoxides by Rh-catalyzed hydrogenation: A combined theoretical and experimental mechanistic study

Doi:10.1021/ja409824b
(2014)
Selective Suzuki-Miyaura monocouplings with symmetrical dibromoarenes and aryl ditriflates for the one-pot synthesis of unsymmetrical triaryls

Doi:10.1002/ejoc.201400090
(2014)
Synthesis of ganglioside lactams corresponding to G_M1-, G_M2-, G_M3-, and G_M4-ganglioside lactones

Doi:10.1021/ja00122a002
(1995)
Synthesis of novel s,o-substituted 1,4-benzoquinones

Doi:10.1080/10426507.2013.798787
(2014)
Control of phase-transition behavior and polymerization capability by methyl addition to dialkyl fumarates bearing cyanobiphenyl mesogens

Doi:10.1246/cl.2007.1052
(2007)
Discovery of a novel series of nonacidic benzofuran EP₁ receptor antagonists

Doi:10.1016/j.bmcl.2011.05.047
(2011)

Article Doi