A Concise, General Enantioselective Synthetic Route to 2(R)- and 2(S)-oxirane and Related Epoxides

DOI: 10.1039/c39930000737

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 737 - 738 (1993)

Update date:2022-09-26

Topics:

Authors:

Bennett, Frank

Girijavallabhan, Viyyoor M.

Patel, Naginbhai

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930000737

The title oxiranes were constructed in >95percent enantiomeric excess (e.e.) utilizing a Sharpless asymmetric epoxidation followed by regioselective azide displacement with i)2(N3)2> as the key steps.

Full text of DOI:10.1039/c39930000737

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzoic acid (2S,3S)-3-azido-2-hydroxy-4-phenyl-butyl ester

Cas No:151250-78-1

R&D Labs maybe for 151250-78-1

Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China

Relevant to this article

Synthesis and evaluation of a pleurotin analog

Doi:10.1080/00397919308009864
(1993)
Chemical transformations of phyllocladane (=13β-kaurane) diterpenoids

Doi:10.1002/hlca.200390043
(2003)
Room temperature rapid functionalization of E-H bonds (E = O, N, S) via the metal-ligand cooperation mechanism

Doi:10.1021/ic402315a
(2014)
Synthesis of a 5-deoxypyranoanthracycline: An entry into novel analogs of idarubicin

Doi:10.1016/S0040-4039(00)73625-2
(1993)
Silver sequestration of halides for the activation of Pd(OAc)₂ catalyzed Mizoroki-Heck reaction of 1,1 and 1,2 - Disubstituted alkenes

Doi:10.1002/aoc.4159
(2018)
Europium catalyzed intramolecular oxazole Diels-Alder reactions for the synthesis of benzopyrano[4,3-b]pyridines and benzo[h]-1,6-naphthyridines

Doi:10.1016/S0040-4039(01)80397-X
(1989)

Article Doi