1,2-Dibromoethane and KI mediated α-acyloxylation of ketones with carboxylic acids

DOI: 10.1016/j.cclet.2019.08.052

Source and publish data:

Chinese Chemical Letters p. 711 - 714 (2020)

Update date:2022-09-26

Topics:

Authors:

Wang, Xujie

Li, Gangsheng

Yang, Yanan

Jiang, Jianshuang

Feng, Ziming

Zhang, Peicheng

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Article abstract of DOI:10.1016/j.cclet.2019.08.052

The 1,2-dibromoethane- and KI-mediated α-acyloxylation of ketones is reported in moderate to good yield without the use of transition metals and strong oxidants. Various acids are well tolerated with wide functional group compatibility. An 1,2-dibromoethane- and KI-catalysed reaction mechanism is proposed based on the results of control experiments.

Full text of DOI:10.1016/j.cclet.2019.08.052

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