Retentive Solvolysis. Part 14. The Methanol-perturbed Phenolysis of Optically Active 2,2-Dimethyl-1-(p-methoxyphenyl)propyl p-Nitrobenzoate. The Mechanism and the Structure of the Second Ion-pair Intermediate

DOI: 10.1039/P29880001875

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1875 - 1884 (1988)

Update date:2022-08-02

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Authors:

Kinoshita, Tomomi

Komatsu, Koichi

Ikai, Keizo

Kashimura, Tsugunori

Tanikawa, Shogo

et al. et al.

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Article abstract of DOI:10.1039/P29880001875

The polarimetric and titrimetric rate constants have been measured for the solvolysis of optically active 2,2-dimethyl-1-(p-methoxyphenyl)propyl p-nitrobenzoate (ROPNB) in phenol-methanol (97:3 w/w).The salt effect of added (Buⁿ)4NClO4 indicate

Full text of DOI:10.1039/P29880001875

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