Novel ruthenium-catalyzed synthesis of 1,3-dioxolan-4-ones from α-hydroxy acids and terminal alkynes via enol esters

DOI: 10.1016/0022-328X(93)83017-P

Source and publish data:

Journal of Organometallic Chemistry p. 133 - 138 (1993)

Update date:2022-09-26

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Authors:

Neveux, Muriel

Seiller, Benedicte

Hagedorn, Frauke

Bruneau, Christian

Dixneuf, Pierre H.

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Article abstract of DOI:10.1016/0022-328X(93)83017-P

α-Hydroxy acids react with terminal alkynes, in the presence of binuclear ruthenium complexes 2 as catalyst precursors, to selectively afford either α-hydroxy enol esters or their cyclization products 1,3-dioxolan-4-ones.

Full text of DOI:10.1016/0022-328X(93)83017-P

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