
Journal of Organic Chemistry p. 5994 - 5999 (1993)
Update date:2022-08-04
Topics:
El-Barbary, Ahmed A.
Khodair, Ahmed I.
Pedersen, Erik B.
Hydantoin nucleosides were synthesized from a protected methyl 2-deoxy-D-ribofuranoside in a Friedel-Crafts catalyzed silyl-Hilbert-Johnson reaction as modified by Vorbrueggen.Atypical byproducts are accounted for by assuming the initial step being a ring opening of the sugar to give an acyclic glycos-1-yl cation.
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