Tetrahedron Letters p. 4997 - 5000 (1993)
Update date:2022-08-03
Topics:
Kasnar, Biserka
Skaric, Vinko
Klaic, Branimir
Zinic, Mladen
The "double headed" nucleosides 10, 11 and 13 bearing pyrimidine or purine bases attached on C-1 and C-5 positions of single ribose unit have been synthesized following a new synthetic strategy.The strategy rests on the introduction of the first nucleobase at C-5 position of the ribose unit giving "reversed" nucleoside and the subsequent attachment of the second base at C-1 position of the ribose, by classical glycosylation reaction.This order of the base attachments gave much better yields on the "double headed" nucleosides then previously known C-1 then C-5 order of attachments.
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