Silylmethylene radical cyclization. A stereoselective approach to branched sugars

DOI: 10.1016/0008-6215(83)85005-8

Source and publish data:

Carbohydrate Research p. 247 - 258 (1993)

Update date:2022-09-26

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Authors:

Pedretti, Valerie

Mallet, Jean-Maurice

Sinay, Pierre

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Article abstract of DOI:10.1016/0008-6215(83)85005-8

Ethyl 6-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside (2) was converted, in three steps and in 73percent overall yield, into ethyl 6-O-benzyl-2,3-dideoxy-3-C-(hydroxymethyl)-α-D-ribo-hex-2-enopyranoside.This transformation involved silylation of 2

Full text of DOI:10.1016/0008-6215(83)85005-8

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