Total synthesis of the carbohydrate-protein linkage region common to several mammalian proteoglycans

Article abstract of DOI:10.1016/0008-6215(83)85009-5

A stereocontrolled synthesis of β-D-GlcpA-(1->3)-β-D-Galp-(1->3)-β-D-Galp-(1->4)-β-D-Xylp-(1->O)L-Ser-Gly, the common glycopeptide sequence of the carbohydrate-protein linkage region of most mammalian proteoglycans, was achieved by use of O-<2-(trimethyls