Synthesis and Evolution of Phosphanylcarbene-Borane Adducts

DOI: 10.1039/c39930001354

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1354 - 1355 (1993)

Update date:2022-07-29

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Authors:

Alcaraz, Gilles

Reed, Robert

Baceiredo, Antoine

Bertrand, Guy

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Article abstract of DOI:10.1039/c39930001354

Photolysis of (trimethylsilyl)diazomethane leads to the corresponding stable carbene 1b, which reacts with triethylborane affording a borane-carbene adduct 2b, characterized by spectroscopy in solution before rearrangemen

Full text of DOI:10.1039/c39930001354

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