Heterocycles p. 1411 - 1424 (1993)
Update date:2022-09-26
Topics:
Hanessian, Stephen
Bennani, Youssef L.
Leblanc, Yves
A variety of acyclic and cyclic aldehydes and ketones can be converted into the corresponding alkylidene, benzylidene and methoxycarbonyl alkylidene derivatives by treatment with 1,3,2-diazaphospholidine-2-alkyl-1,3-dimethyl 2-oxides (α-alkyl cyclic phosphonamides) under mild conditions.This olefination method is particularly useful in the case of enolizable carbonyl compounds.
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(2015)Doi:10.1002/jhet.5570300540
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(2010)
