Carbonyl Insertion and Reductive Elimination Chemistry of Tungsten(II) Alkoxides and Aryloxides

DOI: 10.1039/c39930001432

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1432 - 1434 (1993)

Update date:2022-08-03

Topics:

Authors:

Buffin, Brian P.

Arif, Atta M.

Richmond, Thomas G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001432

Carbonyl insertion into the W-O bond in a series of novel W^II alkoxides and aryloxides, containing a tridentate monoanionic ligand, results in the generation of alkoxycarbonyl- and aryloxycarbonyl-groups, which readily reductively eliminate to form new C-C bonds; in contrast, carbon dioxide insertion into the W-OMe alkoxide bond generates an η¹-carbonate ligand, which retains coordination to the metal centre.

Full text of DOI:10.1039/c39930001432

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{W(CO)4(C₇H₆COOCH₃)(CH₃NCH₂CH₂N(CH₃)2)}

Cas No:152978-31-9

R&D Labs maybe for 152978-31-9

shanghai jinshan pharmaceutical Co.,Ltd

Contact:021-57363011，13681638167

Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Shanghai Norky Pharmaceutical Co., LTD.

website:http://www.norkypharm.com

Contact:86-21-61075300

Address:1165 Jiangning Road, Office 1502, Shanghai, China
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Jai Radhe Sales

website:http://www.jairadhesales.com

Contact:0091-79-26431096

Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
XZL BIO-TECHNOLOGY CO., LTD.

Contact:0086 533 2282832

Address:Zibo，Shandong

Relevant to this article

Novel Series of TSAO-T Derivatives. Synthesis and Anti-HIV-1 Activity of 4-, 5-, and 6-Substituted Pyrimidine Analogues

Doi:10.1021/jm00030a004
(1994)
Synthesis of New Metallomesogens containing a Metal 4-Substituted-piperazine-1-dithiocarboxylate Core

Doi:10.1039/c39930001442
(1993)
Detection of protein S-sulfhydration by a tag-switch technique

Doi:10.1002/anie.201305876
(2014)
A new approach to dihydrobenzofurans and dihydrobenzopyrans (chromans) based on the intramolecular trapping by alcohols of benzynes generated from 7-substituted-1-aminobenzotriazoles

Doi:10.1016/S0040-4020(00)00021-1
(2000)
Asymmetric Synthesis by Enzymatic Hydrolysis of Prochiral Dienol Diacetate.

Doi:10.1016/S0957-4166(00)82222-3
(1993)
Studies of Phosphazenes. Part 34. Group 6 Metal Carbonyl Complexes of Bis(pyrazolyl)cyclotriphosphazenes

Doi:10.1039/DT9940000063
(1994)

Article Doi