Carbonyl Insertion and Reductive Elimination Chemistry of Tungsten(II) Alkoxides and Aryloxides

DOI: 10.1039/c39930001432

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1432 - 1434 (1993)

Update date:2022-08-03

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Authors:

Buffin, Brian P.

Arif, Atta M.

Richmond, Thomas G.

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Article abstract of DOI:10.1039/c39930001432

Carbonyl insertion into the W-O bond in a series of novel W^II alkoxides and aryloxides, containing a tridentate monoanionic ligand, results in the generation of alkoxycarbonyl- and aryloxycarbonyl-groups, which readily reductively eliminate to form new C-C bonds; in contrast, carbon dioxide insertion into the W-OMe alkoxide bond generates an η¹-carbonate ligand, which retains coordination to the metal centre.

Full text of DOI:10.1039/c39930001432

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