Asymmetric Synthesis by Enzymatic Hydrolysis of Prochiral Dienol Diacetate.

DOI: 10.1016/S0957-4166(00)82222-3

Source and publish data:

Tetrahedron Asymmetry p. 2447 - 2450 (1993)

Update date:2022-08-03

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Authors:

Duhamel, Pierre

Renouf, Philippe

Cahard, Dominique

Yebga, Albert

Poirier, Jean-Marie

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Article abstract of DOI:10.1016/S0957-4166(00)82222-3

Enzymatic hydrolysis of prochiral dienol diacetate 1 by Candida cylindracea lipase (CCL) leads to the keto enol acetate 2 in high yield with an enantiometric excess>98percent.The S configuration of the asymmetric center was assigned.

Full text of DOI:10.1016/S0957-4166(00)82222-3

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