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Preparation of α-Methylene and α-Ethylidene β-Lactams via the Ester Enolate-Imine Condensation Using β-(Dialkylamino) Esters as Starting Materials: Scope and Synthetic Applications

DOI: 10.1021/jo00105a013

Source and publish data:

Journal of Organic Chemistry p. 7994 - 8002 (1994)

Update date:2022-08-03

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Authors:

Alcaide, BenitoAlcaide, Benito

Esteban, GemmaEsteban, Gemma

Martin-Cantalejo, YolandaMartin-Cantalejo, Yolanda

Plumet, JoaquinPlumet, Joaquin

Rodriguez-Lopez, JulianRodriguez-Lopez, Julian

et al.et al.

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Article abstract of DOI:10.1021/jo00105a013

A new, simple procedure for the preparation of appropriately substituted α-methylene and α-ethylidene β-lactams via the ester enolate-imine condensation is described.The method is based on the use of lithium 3-(dialkylamino) ester enolates as synthetic eq

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Full text of DOI:10.1021/jo00105a013

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