Mitsunobu Reaction of 1,5-Anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-hydroxymethyl-hex-1-enitols and 1,5-Anhydro-2-deoxy-4,6-O-protected-hex-1-enitols. A Novel Method for the Synthesis of 2-C-Methylene Glycosides and an Useful Alternative to Ferrier Rearrangeme

Article abstract of DOI:10.1016/0040-4020(94)00939-R

A simple and convenient method for the synthesis of aryl-3,4,6-tri-O-benzyl-2-deoxy-2-methylene-hexopyranosides 5, 6 and 7, glycosides which are not accessible by the conventional Ferrier rearrangement, has been described based on the Mitsunobu reaction o