Aza-Payne Rearrangement of Activated 2-Aziridinemethanols and 2,3-Epoxy Amines under Basic Conditions

DOI: 10.1021/jo00112a028

Source and publish data:

Journal of Organic Chemistry p. 2044 - 2058 (1995)

Update date:2022-09-26

Topics:

Authors:

Ibuka, Toshiro

Nakai, Kazuo

Habashita, Hiromu

Hotta, Yuka

Otaka, Akira

et al. et al.

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Article abstract of DOI:10.1021/jo00112a028

An aza-Payne rearrangement of activated 2-aziridinemethanols with t-BuOK, NaH, or KH at near 0 deg C in common solvents such as THF, toluene, 1,2-dimethoxyethane, 1,4-dioxane, or a mixed solvent of THF-HMPA followed by quenching at -78 deg C gives the cor

Full text of DOI:10.1021/jo00112a028

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