Asymmetric synthesis of cis-hydrindanediones by Diels-Alder reaction of cyclopentenones bearing a 3-sulfonyl-1,3-oxazolidine ring as chiral auxillary

DOI: 10.1016/0040-4039(93)88098-4

Source and publish data:

Tetrahedron Letters p. 6537 - 6540 (1993)

Update date:2022-08-02

Topics:

Authors:

Hoffmann

Bolte Bolte

Berger Berger

Hoppe Hoppe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(93)88098-4

The Diels-Alder reaction of enantiomerically pure 2- and 5-(1,3-oxazolidin-2-yl)-2-cyclopentenones 8 or 14 and 2-(trimethylsilyloxy)-1,3-butadiene 9 under Lewis-acid catalysis yields (after hydrolysis) protected 3,7-dioxohydrindane-carbaldehydes 11 or 16,

Full text of DOI:10.1016/0040-4039(93)88098-4

Products guided by the article

Product name:(S)-5-[(2S,4S)-4-Phenyl-3-(toluene-4-sulfonyl)-oxazolidin-2-yl]-cyclopent-2-enone

Cas No:153730-11-1

R&D Labs maybe for 153730-11-1

Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
XZL BIO-TECHNOLOGY CO., LTD.

Contact:0086 533 2282832

Address:Zibo，Shandong
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road

Relevant to this article

Synthesis of the lipophilic antifolate piritrexim via a palladium(0)-catalyzed cross-coupling reaction

Doi:10.1021/jo040268z
(2005)
Doi:10.1021/ja01600a075
()
Regioselective syntheses of 3-aminomethyl-5-substituted isoxazoles: A facile and chemoselective reduction of azide to amino by sodium borohydride using 1,3-propanedithiol as a catalyst

Doi:10.1016/S0040-4039(00)60386-6
(1993)
Synthesis of 1-palmitoyl-2-hexadecyl-sn-glycero-3-phospholine (PHPC)

Doi:10.1016/0009-3084(93)90001-J
(1993)
Heteroatom exchange reactions in imidoosmium(II) systems: Cleavage of Os-N multiple bonds and formation of Os-X bonds (X = O, S, C)

Doi:10.1021/om00015a021
(1994)
REGIOSPECIFIC SYNTHESIS OF α-ARYLSULFONOXY KETONES FROM KETONE DERIVATIVES

Doi:10.1016/S0040-4039(00)85333-2
(1986)

Article Doi